The following Aldermen served as Mayor of Enfield Muncipal Council from 1889 to 1949. * denotes service as Member of NSW Parliament.
- 1889-90: James Eve*
- 1891: Thomas Hodson
- 1892: Herman Henry Groth
- 1893: George Westbrook
- 1894-5: Henry G. Lipscomb
- 1896: George W. Eaton
- 1897-1902: Thomas Hodson
- 1903: Henry C. Pilcher
- 1904-7: James MacKay
- 1908: Albert E. Weil
- 1909: James MacKay
- 1910-1913: George B Phillips
- 1914: Frederick Williams
- 1915-1917: Ebenezer Ford
- 1917-18: Frederick Williams
- 1919: Adrian Burgess
- 1920-29: Ebenezer Ford
- 1930-35: Stanley A. Lloyd
- 1936-7: Reuben H Jenner
- 1938: William E Flockhart
- 1939: James Mooney
- 1940: James W Parkes
- 1941-6: Thomas E Cooke
- 1947: William J Sky
- 1948: Thomas E Cooke.
James Eve was Member of the Legislative Assembly (Electorate of Canterbury) from September 1891 to June 1894.
Stanley Lloyd was Member of the Legislative Assembly (Electorate of Concord) from 1932-1941.